By A.G. Sykes
Advances in Inorganic Chemistry offers well timed and informative summaries of the present development in numerous topic parts inside of inorganic chemistry, starting from bioinorganic to reliable kingdom.
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57Fe-MGssbauer spectra of their mixed-valence cation indicates the presence of valence-trapping on a time scale of 10e7s. There is one report of the redox properties of poly(ferrocenylene) by Oyama et al. 8 V vs. SSCE (70). Contrary to the continuous advances in the study of poly(l,l’-ferrocenylene), investigation of other related polymetallocenylenes has been retarded. Oligo(l,Z-ferrocenylene)s (18, n = 335) have been synthesized by the Ullmann coupling of iodoferrocene and 1,2-diiodoferrocene (71,72).